2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸的合成及其应用——多元显色体系光度法测定金属材料中的镍   总被引：2，自引：0，他引：2  

樊学忠  吴斌才  刘恒椽  吴诚 《岩矿测试》1993,(1):31-34

报道了新显色剂2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸(BTACB)的合成,研究了在十二烷基硫酸钠(NaLS)存在下Ni~(2+)与BTACB形成蓝紫色配合物的条件,其λ_(max)~(MR)=600nm,ε=2.79×10~4L·mol~(-1)·cm~(-1),Ni在0～0.6μg/ml范围内服从比尔定律,反应具有一定的选择性。方法已用于直接测定铝合金、纯镁及含一定量Co的钢铁中痕量Ni和经萃取分离后测定纯钴中痕量Ni。  相似文献   

X射线荧光光谱法测定叶腊石中的铝铁钾钠   总被引：1，自引：0，他引：1  

郭寿兴  吴玉庆 《岩矿测试》1993,12(4):290-292

采用同一矿区已知成分含量的叶腊石配制标样系列，克服了粉末法测定叶腊石中Ａｌ２Ｏ３，Ｆｅ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。  相似文献   

743离子交换快速分离—等离子体光谱法同时测定十五个稀土元素   总被引：1，自引：0，他引：1  

吴锡凤  蒋铁珊 《铀矿地质》1993,(5)

本文研制了适用于地质样品中15个稀土元素分析的快速方法。样品经碱熔沉淀分离和743阳离子交换树脂分离富集将稀土元素制备成溶液用等离子体光谱法(ICP-AES)进行测量。方法检出限为0.002-0.3μg/g,当稀土元素含量为0.5-80,μg/g时,方法相对标准偏差为15％-2％。本方法经过多年的样品分析考验以及不断的改进和完善,证明方法简便快速,分析数据稳定可靠,能很好地满足地质样品中15个稀土分量测定的要求。  相似文献   

The phase velocities of Rayleigh waves and the lateral variation of lithospheric structure in Tibetan Plateau   总被引：1，自引：0，他引：1  

Guo-Ying Chen  Rong-Sheng Zeng  Francis T. Wu  Xiao-Lan Su 《地震学报(英文版)》1993,6(2):289-297

According to a Sino-U. S. joint project, eleven broadband digital PASSCAL seismometers had been deployed inside the Tibetan Plateau, of which 7 stations were on the profile from Lhasa to Golmud and other 4 stations situated at Maxin, Yushu, Xigatze and Linzhi. Dispersions and phase velocities of the Rayleigh surface waves (10s–120s) were obtained on five paths distributed in the different blocks of Tibetan Plateau. Inversions of the S-wave velocity structures in Songpan-Ganzi block, Qiang-Tang block, Lhasa block and the faulted rift zone were obtained from the dispersion data. The results show that significant lateral variation of the S-wave velocity structures among the different blocks exists. The path from Wenquan to Xigatze (abbreviated as Wndo-Xiga) passes through the rift-zone of Yadong-Anduo. The phase velocities of Rayleigh waves from 10s to 100s on this path are significantly higher than that on other paths. The calculated mean crustal velocity on this path is 3.8 km/s, much greater than that on other paths, where mean crustal velocities of 3.4–3.5 km/s are usually observed. Low velocity zones with different thicknesses and velocities are observed in the middle-lower crust for different paths. Songpan-Ganzi block, located in the northern part of Tibetan Plateau is characterized by a thinner crust of 65 km thick and a prominent low velocity zone in the upper mantle. The low velocity zone with a velocity of 4.2 km/s is located at a depth form 115 km to 175 km. While in other blocks, no low velocity zone in the upper mantle is observed. The value of Sn in Songpan-Ganzi is calculated to be 4.5 km/s, while those in Qiang-Tang and Lhasa blocks are about 4.6 km/s. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,14, Supp., 566–573, 1992.  相似文献   

Preliminary study of crust-upper mantle structure of the Tibetan Plateau by using broadband teleseismic body waveforms   总被引：2，自引：0，他引：2  

Lu-Pei Zhu  Rong-Sheng Zeng  Francis T. Wu  Thomas J. Owens  George E. Randall 《地震学报(英文版)》1993,6(2):305-316

As part of a joint Sino-U.S. research project to study the deep structure of the Tibetan Plateau, 11 broadband digital seismic recorders were deployed on the Plateau for one year of passive seismic recording. In this report we use teleseimic P waveforms to study the seismic velocity structure of crust and upper mantle under three stations by receiver function inversion. The receiver function is obtained by first rotating two horizontal components of seismic records into radial and tangential components and then deconvolving the vertical component from them. The receiver function depends only on the structure near the station because the source and path effects have been removed by the deconvolution. To suppress noise, receiver functions calculated from events clustered in a small range of back-azimuths and epicentral distances are stacked. Using a matrix formalism describing the propagation of elastic waves in laterally homogeneous stratified medium, a synthetic receiver function and differential receiver functions for the parameters in each layer can be calculated to establish a linearized inversion for one-dimensional velocity structure. Preliminary results of three stations, Wen-quan, Golmud and Xigatze (Coded as WNDO, TUNL and XIGA), located in central, northern and southern Plateau are given in this paper. The receiver functions of all three stations show clear P-S converted phases. The time delays of these converted phases relative to direct P arrivals are: WNDO 7.9s (for NE direction) and 8.3s (for SE direction), TUNL 8.2s, XIGA 9.0s. Such long time delays indicate the great thickness of crust under the Plateau. The differences between receiver function of these three station shows the tectonic difference between southern and north-central Plateau. The waveforms of the receiver functions for WNDO and TUNL are very simple, while the receiver function of XIGA has an additional midcrustal converted phase. The S wave velocity structures at these three stations are estimated from inversions of the receiver function. The crustal shear wave velocities at WNDO and TUNL are vertically homogeneous, with value between 3.5–3.6 km/s down to Moho. This value in the lower crust is lower than the normal value for the lower crust of continents, which is consistent with the observed strong Sn attenuation in this region. The velocity structure at XIGA shows a velocity discontinuity at depth of 20 km and high velocity value of 4.0 km/s in the midcrust between 20–30 km depth. Similar results are obtained from a DSS profile in southern Tibet. The velocity under XIGA decreases below a depth of 30 km, reaching the lowest value of 3.2 km/s between 50–55 km. depth. This may imply that the Indian crust underthrusts the low part of Tibetan crust in the southern Plateau, forming a “double crust”. The crustal thickness at each of these sites is: WNDO, 68 km; TUNL, 70 km; XI-GA, 80 km. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,14, Supp., 581–592, 1992.  相似文献   

Surface complexation at hydrous fluorapatite     

Willis Forsling  Liuming Wu 《Aquatic Sciences - Research Across Boundaries》1993,55(4):336-346

The adsorption of H⁺, OH^– and ARS (Alizarin Red S) onto hydrous fluorapatite surfaces and Ca²⁺—ARS complexation in solution were studied by means of combined potentiometric and spectrophotometric titrations, as well as zeta potential and FT-IR measurements. Corresponding equilibrium constants of surface and solution reactions are determined. The application in flotation processes is discussed.  相似文献   

油气地化指标得分和方法在油气化探异常评价中的应用     

吴锡生  李景朝 《吉林大学学报(地球科学版)》1993,(3)

以我国华北某油区油气勘探为例,介绍了油气地球化学异常评价标志及依据,并利用这些评价标志——异常形态、异常组合、异常规模(N4P)、变异系数、构造圈闭等在油气地化异常评价中的作用,给出不同的分值,按评分标准对圈定的异常求出累积得分和,据此对油气化探异常所圈定的远景区进行排序,为进一步的油气勘查提供地球化学依据,并取得了较好的效果。  相似文献   

攀钢,攀矿场地边坡地震稳定性研究     

马声浩  雷建成 《四川地震》1993,(2):1-11

本文在总结分析攀钢、攀矿昔格达层滑坡基本特征的基础上,对区内滑坡进行了地震稳定性计算,给出了经不同方法治理后的滑坡的地震稳定系数;同时采用“因子迭加”方法对究研区进行边坡稳定性区划,划分出相对的稳定区、欠稳定区和不稳定区,为抗震减灾和土地的开发利用提供了科学依据。  相似文献   

1614年平遥—榆社间61／2级地震的讨论     

武烈 《山西地震》1993,(3):30-34

通过对1614年平遥榆社间6(1/2)级地震的进一步研究,认为前人确定这次地震时所用的史料疑点较多,所确定的基本参数也问题较大.得出是两次地震事件的结论:一次是1614年10月15日(万历四十二年九月十三日),地点武乡,震级约为5(1/2)级;一次是1614年10月23日(万历四十二年九月二十一日),地点榆社,震级约5(3/4)级.  相似文献   

塘古坳陷构造—沉积演化及其油气勘探方向     

苏 洲邬光辉  张艳秋周 波曹颖辉  张慧芳吴梅莲 《地质科学》1958,55(1):43-56

塔里木盆地塘古坳陷历经20余年勘探而成效甚微,在新的地震与钻井资料基础上,通过地层沉积对比、构造解析重新认识塘古坳陷的形成与演化,及其对勘探方向的指示研究,结果表明：1）塘古地区存在基底古隆起,寒武系自塔中向南逐渐减薄;2）本区钻揭中-下奥陶统碳酸盐岩地层连续,不存在寒武系—中奥陶统的台槽;3）上奥陶统良里塔格组沉积期在东西两侧发育巨厚的台地边缘相带,而坳陷区相变为盆地泥岩相;4）北东向冲断构造具有分层变形特点,断裂活动始于晚奥陶世早期,冲断推覆作用主要形成于奥陶纪末。结果揭示塘古坳陷经历4期构造关键演化期：1）寒武—中奥陶世与塔中连为一体的碳酸盐岩台地发育期;2）上奥陶统良里塔格组沉积期受控东南板缘俯冲与碰撞作用的台盆形成期;3）奥陶纪末强烈沉降的挤压挠曲盆地定型期;4）志留纪—泥盆纪的构造改造期。该结果为盆地构造古地理研究与深层油气评价提供了基础,并提出了勘探新方向。  相似文献